International Organization for Standardization

Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 2: Determination of selected elements including uranium isotopes - Second Edition
 N 17294-2

Annotation

This part of ISO 17294 specifies a method for the determination of the elements aluminium, antimony, arsenic, barium, beryllium, bismuth, boron, cadmium, caesium, calcium, cerium, chromium, cobalt, copper, dysprosium, erbium, gadolinium, gallium, germanium, gold, hafnium, holmium, indium, iridium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, mercury, molybdenum, neodymium, nickel, palladium, phosphorus, platinum, potassium, praseodymium, rubidium, rhenium, rhodium, ruthenium, samarium, scandium, selenium, silver, sodium, strontium, terbium, tellurium, thorium, thallium, thulium, tin, tungsten, uranium and its isotopes, vanadium, yttrium, ytterbium, zinc and zirconium in water (for example, drinking water, surface water, ground water, waste water and eluates).

Taking into account the specific and additionally occurring interferences, these elements can also be determined in digests of water, sludges and sediments (for example, digests of water as described in ISO 15587-1 or ISO 15587-2).

The working range depends on the matrix and the interferences encountered. In drinking water and relatively unpolluted waters, the limit of quantification (xLQ) lies between 0,002 ?g/l and 1,0 ?g/l for most elements (see Table 1). The working range typically covers concentrations between several pg/l and mg/l depending on the element and pre-defined requirements.

The quantification limits of most elements are affected by blank contamination and depend predominantly on the laboratory air-handling facilities available on the purity of reagents and the cleanliness of glassware.

The lower limit of quantification is higher in cases where the determination suffers from interferences (see Clause 5) or memory effects (see ISO 17294-1:2004, 8.2).