ASTM International

Standard Test Method for Boiling Point Distribution of Samples with Residues Such as Crude Oils and Atmospheric and Vacuum Residues by High Temperature Gas Chromatography
 N D7169

Annotation

This test method covers the determination of the boiling point distribution and cut point intervals of crude oils and residues by using high temperature gas chromatography. The amount of residue (or sample recovery) is determined using an external standard.

This test method extends the applicability of simulated distillation to samples that do not elute completely from the chromatographic system. This test method is used to determine the boiling point distribution through a temperature of 720°C. This temperature corresponds to the elution of n-C100.

This test method is used for the determination of boiling point distribution of crude oils. This test method uses capillary columns with thin films, which results in the incomplete separation of C4-C8 in the presence of large amounts of carbon disulfide, and thus yields an unreliable boiling point distribution corresponding to this elution interval. In addition, quenching of the response of the detector employed to hydrocarbons eluting during carbon disulfide elution, results in unreliable quantitative analysis of the boiling distribution in the C4-C8 region. Since the detector does not quantitatively measure the carbon disulfide, its subtraction from the sample using a solvent-only injection and corrections to this region via quenching factors, results in an approximate determination of the net chromatographic area. A separate, higher resolution gas chromatograph (GC) analysis of the light end portion of the sample may be necessary in order to obtain a more accurate description of the boiling point curve in the interval in question (see Appendix X1).

This test method is also designed to obtain the boiling point distribution of other incompletely eluting samples such as atmospheric residues, vacuum residues, etc., that are characterized by the fact that the sample components are resolved from the solvent.