ASTM International

Standard Test Method for Kinetic Parameters for Thermally Unstable Materials by Differential Scanning Calorimetry Using the Kissinger Method
 N E2890

Annotation

This test method describes the determination of the kinetic parameters of Arrhenius activation energy and preexponential factor using the Kissinger variable heating rate iso-conversion method (1, 2)2 and activation energy and reaction order by the Farjas method (3) for thermally unstable materials. The test method is applicable to the temperature range from 300 to 900 K (27 to 627°C).

Both nth order and accelerating reactions are addressed by this method over the range of 0.5 < n < 4 and 1 < p < 4 where n is the nth order reaction order and p is the Avrami reaction order (4). Reaction orders n and p are determined by the Farjas method (3).

This test method uses the same experimental conditions as Test Method E698. The Flynn/Wall/Ozawa data treatment of Test Method E698 may be simultaneously applied to these experimental results.

The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

There is no ISO equivalent to this standard.

This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

2 The boldface numbers in parentheses refer to the list of references at the end of this standard.